Integrin activation enables rapid detection of functional Vδ1+ and Vδ2+ γδ T cells
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DOI: 10.1002/eji.202149682
Abstract: Conformational change of the β2 integrin lymphocyte function‐associated antigen 1 (LFA‐1) is an early marker of T cell activation. A protocol using the mAb clone m24 recognizing the active, extended high‐affinity conformation has been previously… read more here.
Keywords: activation; activation enables; detection; functional cells ... See more keywords
In situ silane activation enables catalytic reduction of carboxylic acids.
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DOI: 10.1039/d1cc03396d
Abstract: We describe a catalytic system for the conversion of carboxylic acids into alcohols using substoichiometric zinc acetate and N-methyl morpholine, in combination with phenylsilane as the nominal terminal reductant. Reaction monitoring by 19F NMR spectroscopy… read more here.
Keywords: activation enables; enables catalytic; situ silane; silane activation ... See more keywords
Metal-Free C(sp3)–Si Activation Enables Regiocontrolled [4+2] Cycloaddition to Benzosilacycloethers
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DOI: 10.1039/d5gc03044g
Abstract: We herein report a sustainable, transition-metal-free strategy for the inverse site-selective [4+2] cycloaddition of benzosilacyclobutanes with activated ketones, enabled by the dual role of DMSO as a mild Lewis base... read more here.
Keywords: enables regiocontrolled; metal free; cycloaddition; sp3 activation ... See more keywords