Articles with "activation energies" as a keyword



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Apparent activation energies of protein–protein complex dissociation in the gas–phase determined by electrospray mass spectrometry

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Published in 2017 at "Analytical and Bioanalytical Chemistry"

DOI: 10.1007/s00216-017-0603-4

Abstract: AbstractWe have developed a method to determine apparent activation energies of dissociation for ionized protein–protein complexes in the gas phase using electrospray ionization mass spectrometry following the Rice-Ramsperger-Kassel-Marcus quasi-equilibrium theory. Protein–protein complexes were formed in… read more here.

Keywords: protein; gas phase; activation energies; protein protein ... See more keywords
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Quantifying the activation energies of ROS-induced NOx conversion: Suppressed toxic intermediates generation and clarified reaction mechanism

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Published in 2019 at "Chemical Engineering Journal"

DOI: 10.1016/j.cej.2019.122026

Abstract: Abstract The generation and transformation of reactive oxygen species (ROS) is a key parameter in catalyzing photocatalytic gas-phase oxidation reactions for environmental remediation. Thus the determination, quantification and kinetic tracking of ROS are conclusively required… read more here.

Keywords: ros induced; generation; conversion; activation energies ... See more keywords
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Synthesis, spectral characterization and study of thermal behavior kinetics by thermogravimetric analysis of metal complexes derived from salicylaldehyde and alkylamine

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Published in 2017 at "Journal of Molecular Structure"

DOI: 10.1016/j.molstruc.2017.04.029

Abstract: Abstract Cobalt(III)- and copper(II)-Schiff base complexes have been prepared by reaction of the bidentate Schiff base ligand (HL: 2-(4-methoxyphenyl)-1-iminosalicylidenethane) with cobalt(II) and copper(II) chlorides. Structures of the synthesized complexes have been characterized by various physicochemical… read more here.

Keywords: thermogravimetric analysis; analysis; activation energies; metal complexes ... See more keywords
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Molecular vibrations, activation energies of trapped carriers and additional structure in thermoluminescence of organic polymers

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Published in 2017 at "Synthetic Metals"

DOI: 10.1016/j.synthmet.2017.10.007

Abstract: Abstract Manifestations of optical vibrations in thermoluminescence of organic polymers were observed. Thermoluminescence curves and Raman spectra of the polymers which have different degrees of ordering: poly(di-n-hexylsilane), poly(methylphenylsilane) and poly(di-n-penthylsilane) were measured and the features… read more here.

Keywords: organic polymers; thermoluminescence organic; activation energies; thermoluminescence ... See more keywords
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Rapid Determination of Activation Energies for Gas-Phase Protein Unfolding and Dissociation in a Q-IM-ToF Mass Spectrometer.

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Published in 2020 at "Journal of the American Society for Mass Spectrometry"

DOI: 10.1021/jasms.9b00055

Abstract: Ion mobility-mass spectrometry has emerged as a powerful tool for interrogating a wide variety of chemical systems. Collision-induced unfolding (CIU), typically performed in time-of-flight instruments, has been utilized to obtain valuable qualitative insight into protein… read more here.

Keywords: protein; dissociation; activation energies; mass ... See more keywords
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Application of a Non-Isothermal Numerical-Analytical Model to Determine the Kinetics of Austenite Formation in a Silicon Alloyed Steel

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Published in 2022 at "Materials"

DOI: 10.3390/ma15041376

Abstract: A non-isothermal transformation model was proposed to determine the austenite formation kinetics in a steel alloyed with 2.6% wt. Si by dilatometric analysis, considering that the nucleation mechanism does not change with the heating rate.… read more here.

Keywords: steel; activation energies; non isothermal; model ... See more keywords
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Metal Cluster Size-Dependent Activation Energies of Growth of Single-Chirality Single-Walled Carbon Nanotubes inside Metallocene-Filled Single-Walled Carbon Nanotubes

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Published in 2021 at "Nanomaterials"

DOI: 10.3390/nano11102649

Abstract: By combining in situ annealing and Raman spectroscopy measurements, the growth dynamics of nine individual-chirality inner tubes (8,8), (12,3), (13,1), (9,6), (10,4), (11,2), (11,1), (9,3) and (9,2) with diameters from ~0.8 to 1.1 nm are… read more here.

Keywords: energies growth; activation energies; walled carbon; single walled ... See more keywords
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Activation Energies and Temperature Dependencies of the Rates of Crystallization and Melting of Polymers

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Published in 2020 at "Polymers"

DOI: 10.3390/polym12051070

Abstract: The objective of this review paper is to survey the phase transition kinetics with a focus on the temperature dependence of the rates of crystallization and melting, as well as on the activation energies of… read more here.

Keywords: temperature; crystallization melting; activation energies; rates crystallization ... See more keywords