A DFT Survey of the Effects of d‐Electron Count and Metal Identity on the Activation and Functionalization of C−H Bonds for Mid to Late Transition Metals
Sign Up to like & getrecommendations! Published in 2017 at "Israel Journal of Chemistry"
DOI: 10.1002/ijch.201700066
Abstract: The contribution of metal identity to the activation and functionalization of methane by a series of three-coordinate imide complexes is evaluated in silico for a 3-by-3 block of metals from Fe to Pt. Three mechanisms… read more here.
Keywords: activation functionalization; identity activation; transition metals; metal ... See more keywords
Cyclometallated complexes as catalysts for C-H activation and functionalization.
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DOI: 10.1039/d1cc05195d
Abstract: The development of novel catalysts for C-H activation reactions with increased reactivity and improved selectivities has been attracting significant interest over the last two decades. More recently, promising results have been developed using tridentate pincer… read more here.
Keywords: complexes catalysts; activation functionalization; cyclometallated complexes; activation ... See more keywords
Advances and developments in transition metal-free benzylic C(sp3)–H activation/functionalization reactions
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DOI: 10.1039/d5ra00361j
Abstract: Transition metal-free C(sp3)–H activation of toluene derivatives is known as a green and sustainable methodology for constructing carbon–carbon and carbon–heteroatom bonds. Benzylic C(sp3)–H activation/functionalization bond formation can be carried out in the presence of organic/inorganic… read more here.
Keywords: sp3 activation; transition metal; activation functionalization; activation ... See more keywords