CO2 activation by ligand-free manganese hydrides in a parahydrogen matrix.
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DOI: 10.1039/d0cc08256b
Abstract: Manganese formate complexes, HMn(η2-O2CH) and Mn(η2-O2CH), are formed through MnH2 and MnH reactions with CO2 in solid parahydrogen and identified by matrix infrared spectroscopy with the basis of isotopic substitutions and theoretical frequency calculations. The… read more here.
Keywords: ligand free; free manganese; hydrides parahydrogen; activation ligand ... See more keywords