Insights into the Activation Mode of α‐Carbonyl Sulfoxonium Ylides in Rhodium‐Catalyzed C−H Activation: A Theoretical Study
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DOI: 10.1002/open.202100254
Abstract: Abstract A computational study has been performed to investigate the mechanism of RhIII‐catalyzed C−H bond activation using sulfoxonium ylides as a carbene precursor. The stepwise and concerted activation modes for sulfoxonium ylides were investigated. Detailed… read more here.
Keywords: activation; insights activation; sulfoxonium ylides; activation mode ... See more keywords
Streptocyanine as an activation mode of amine catalysis for the conversion of pyridine rings to benzene rings
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DOI: 10.1039/d2sc06225a
Abstract: Amine catalysts have emerged as an invaluable tool in organic synthesis. Iminium, enamine, and enamine radical cation species are representative activation modes of amine catalysis. However, the development of new amine catalysis activation modes that… read more here.
Keywords: amine catalysis; pyridine rings; activation mode; activation ... See more keywords
A PAM-free CRISPR/Cas12a ultra-specific activation mode based on toehold-mediated strand displacement and branch migration
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DOI: 10.1093/nar/gkac886
Abstract: Abstract CRISPR (clustered regularly interspaced short palindromic repeats) technology has achieved great breakthroughs in terms of convenience and sensitivity; it is becoming the most promising molecular tool. However, only two CRISPR activation modes (single and… read more here.
Keywords: crispr cas12a; crispr; toehold mediated; activation mode ... See more keywords