Biomimetic Activation of Molecular Oxygen with a Combined Metalloporphyrinic Framework and Co‐catalyst Platform
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DOI: 10.1002/cctc.201601606
Abstract: Cytochromes P450 are powerful biocatalysts that present high catalytic efficiency in the aerobic oxidation of hydrocarbons under mild conditions. Even though metal–organic frameworks (MOFs), consisting of biomimetic metalloporphyrin moieties, are highly active in a number of… read more here.
Keywords: activation molecular; mild conditions; platform; aerobic oxidation ... See more keywords
Reductive Electrochemical Activation of Molecular Oxygen Catalyzed by an Iron-Tungstate Oxide Capsule: Reactivity Studies Consistent with Compound I Type Oxidants
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DOI: 10.1021/acscatal.0c00897
Abstract: The reductive activation of molecular oxygen catalyzed by iron-based enzymes toward its use as an oxygen donor is paradigmatic for oxygen transfer reactions in nature. Mechanistic studies on these ... read more here.
Keywords: activation molecular; oxygen; catalyzed iron; oxygen catalyzed ... See more keywords