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Published in 2018 at "Dalton transactions"
DOI: 10.1039/c8dt00236c
Abstract: A series of density functional theory calculations have been carried out to investigate the detailed mechanisms of C-H activation and oxidation reactions, and further to disclose the distinct effects of mononuclear- and binuclear-palladium on these…
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Keywords:
mechanisms activation;
oxidation;
oxidation reactions;
pdii ... See more keywords
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Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc00242f
Abstract: Mechanochemical impact induces oxidation of U(IV)O2 in presence of alkali metal peroxides Li2O2 and Na2O2 during liquid-assisted grinding, resulting in respective alkali U(VI) triperoxide phases (e.g. Na4[UO2(O2)3]ยท9H2O), based on powder X-ray diffraction analysis, solid- and…
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Keywords:
spectroscopy;
oxidation;
mechanochemical activation;
activation oxidation ... See more keywords