Catalytic Activation of Unstrained C(Aryl)-C(Alkyl) Bonds in 2,2'-Methylenediphenols.
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DOI: 10.1021/jacs.1c13342
Abstract: Catalytic activation of unstrained and nonpolar C-C bonds remains a largely unmet challenge. Here, we describe our detailed efforts in developing a rhodium-catalyzed hydrogenolysis of unstrained C(aryl)-C(alkyl) bonds in 2,2'-methylenediphenols aided by removable directing groups.… read more here.
Keywords: unstrained aryl; activation unstrained; bonds methylenediphenols; aryl alkyl ... See more keywords