Palladium-Catalyzed C-S Bond Formation as a Tool for Latent-Active Glycosylation.
Sign Up to like & getrecommendations! Published in 2020 at "Organic letters"
DOI: 10.1021/acs.orglett.0c02090
Abstract: A high-yielding palladium-catalyzed C-S cross-coupling is presented for utilization in carbohydrate chemistry as a key transformation for attachment of a second chelating sulfur atom that allows the exploitation of a latent-active glycosylation strategy with Cu(OTf)2… read more here.
Keywords: latent active; bond formation; active glycosylation; palladium catalyzed ... See more keywords
Keep Sugar Away to Stay Active: Glycosylation of Methyl Salicylate Shuts Down Systemic Signaling
Sign Up to like & getrecommendations! Published in 2019 at "Plant Physiology"
DOI: 10.1104/pp.19.00747
Abstract: Plant hormones are frequently modified by glycosylation, hydroxylation, methylation, and other conjugations, and these modifications can alter the hormone’s activity and stability ([Wang et al., 2019][1]). The phytohormone salicylic acid orchestrates effective defense and mediates… read more here.
Keywords: away stay; stay active; active glycosylation; sugar away ... See more keywords