Facile preparation of optically active helical polycarbenes with salicylate substituents and their postpolymerization modification.
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DOI: 10.1039/d3cc00237c
Abstract: Optically active helical polycarbenes were constructed through the living and controlled helix-sense-selective polymerization (HSSP) of methyl salicylate modified diazoacetate monomer catalysed via π-allylPdCl with chiral phosphine ligands. The obtained helical polycarbenes could undergo postpolymerization modification… read more here.
Keywords: active helical; postpolymerization modification; optically active; helical polycarbenes ... See more keywords