Facile preparation of optically active helical polycarbenes with salicylate substituents and their postpolymerization modification.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d3cc00237c
Abstract: Optically active helical polycarbenes were constructed through the living and controlled helix-sense-selective polymerization (HSSP) of methyl salicylate modified diazoacetate monomer catalysed via π-allylPdCl with chiral phosphine ligands. The obtained helical polycarbenes could undergo postpolymerization modification… read more here.
Keywords: active helical; postpolymerization modification; optically active; helical polycarbenes ... See more keywords
Optically active helical polymers bearing cinchona alkaloid pendants: an efficient chiral organocatalyst for asymmetric Henry reaction
Sign Up to like & getrecommendations! Published in 2025 at "Polymer Chemistry"
DOI: 10.1039/d4py01284d
Abstract: Inspired by the highly efficient and enantioselective reactions catalyzed by biomacromolecules, developing artificial helical polymer-supported catalysts is an attractive and meaningful field. In this work, a series of helical polymers... read more here.
Keywords: bearing cinchona; helical polymers; polymers bearing; active helical ... See more keywords