Reactivity of Aluminum Complexes of Redox-Active Ligand toward N-Heterocyclic Carbene and Its Thione
Sign Up to like & getrecommendations! Published in 2019 at "Organometallics"
DOI: 10.1021/acs.organomet.9b00611
Abstract: The reaction of dialane (dpp-Bian)Al–Al(dpp-Bian) (1) (dpp-Bian is dianion of 1,2-bis[(2,6-diisopropylphenyl)imino]-acenaphthene) with 1 mol equiv of 1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene ... read more here.
Keywords: reactivity aluminum; active ligand; complexes redox; dpp bian ... See more keywords
Redox-active ligand based Mn(I)-catalyst for hydrosilylative ester reduction.
Sign Up to like & getrecommendations! Published in 2021 at "Chemical communications"
DOI: 10.1039/d1cc05614j
Abstract: Herein a Mn(I) catalyst bearing a redox-active phenalenyl (PLY) based ligand is reported for the efficient hydrosilylation of esters to alcohols using the inexpensive silane source polymethylhydrosiloxane (PMHS) under mild conditions. Mechanistic investigations suggest a… read more here.
Keywords: ligand based; based catalyst; active ligand; redox active ... See more keywords