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Published in 2019 at "Organometallics"
DOI: 10.1021/acs.organomet.9b00611
Abstract: The reaction of dialane (dpp-Bian)Al–Al(dpp-Bian) (1) (dpp-Bian is dianion of 1,2-bis[(2,6-diisopropylphenyl)imino]-acenaphthene) with 1 mol equiv of 1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene ...
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Keywords:
reactivity aluminum;
active ligand;
complexes redox;
dpp bian ... See more keywords
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Published in 2021 at "Chemical communications"
DOI: 10.1039/d1cc05614j
Abstract: Herein a Mn(I) catalyst bearing a redox-active phenalenyl (PLY) based ligand is reported for the efficient hydrosilylation of esters to alcohols using the inexpensive silane source polymethylhydrosiloxane (PMHS) under mild conditions. Mechanistic investigations suggest a…
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Keywords:
ligand based;
based catalyst;
active ligand;
redox active ... See more keywords