Nanochannel-based {BaZn}-organic framework for catalytic activity on the cycloaddition reaction of epoxides with CO2 and deacetalization-Knoevenagel condensation.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d1dt04231a
Abstract: Herein, the rare combination of BaII (5s) and ZnII (3d) in the presence of the structure-oriented TDP6- ligand generated the nanochannel-based hybrid material {[(CH3)2NH2]2[BaZn(TDP)(H2O)]·DMF·5H2O}n (NUC-51, H6TDP = 2,4,6-tri(2,4-dicarboxyphenyl)pyridine), which possesses excellent physicochemical characteristics such as… read more here.
Keywords: activity cycloaddition; nanochannel based; deacetalization knoevenagel; knoevenagel condensation ... See more keywords
A highly robust cluster-based indium(III)-organic framework with efficient catalytic activity in cycloaddition of CO2 and Knoevenagel condensation.
Sign Up to like & getrecommendations! Published in 2023 at "Dalton transactions"
DOI: 10.1039/d2dt04043c
Abstract: The efficient catalytic performance displayed by MOFs is decided by an appropriate charge/radius ratio of defect metal sites, large enough solvent-accessible channels and Lewis base sites capable of polarizing substrate molecules. Herein, the solvothermal self-assembly… read more here.
Keywords: efficient catalytic; framework; cluster; catalytic activity ... See more keywords