Synthesis of syn-vicinal diamines via the stereoselective allylation of acyclic chiral α-amino aldimines
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DOI: 10.1016/j.tetlet.2018.12.021
Abstract: Abstract The stereoselective allylation of acyclic chiral α-amino aldimines affording vicinal diamines, mediated by various Lewis acids (TiCl4, SnCl4, MgBr2·OEt2, BF3·OEt2, ZnCl2), is described. The TiCl4-mediated allylation of an α-N-Boc aldimine afforded the allylation product… read more here.
Keywords: allylation acyclic; amino aldimines; allylation; stereoselective allylation ... See more keywords