Platinum(II)-Substituted Phenylacetylide Complexes Supported by Acyclic Diaminocarbene Ligands.
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DOI: 10.1021/acs.inorgchem.2c00510
Abstract: We introduce phosphorescent platinum aryl acetylide complexes supported by tert-butyl-isocyanide and strongly σ-donating acyclic diaminocarbene (ADC) ligands. The precursor complexes cis-[Pt(CNtBu)2(C≡CAr)2] (4a-4f) are treated with diethylamine, which undergoes nucleophilic addition with one of the isocyanides… read more here.
Keywords: platinum substituted; complexes supported; acyclic diaminocarbene; substituted phenylacetylide ... See more keywords