Room Temperature Intermolecular Dearomatization of Arenes by an Acyclic Iminosilylene.
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DOI: 10.1021/jacs.2c10467
Abstract: A novel nontransient acyclic iminosilylene (1), bearing a bulky super silyl group (-SitBu3) and N-heterocyclic imine ligand with a methylated backbone, was prepared and isolated. The methylated backbone is the feature of 1 that distinguishes… read more here.
Keywords: temperature intermolecular; acyclic iminosilylene; dearomatization; intermolecular dearomatization ... See more keywords