Vanadium-Catalyzed Synthesis of Geometrically Defined Acyclic Tri- and Tetrasubstituted Olefins from Propargyl Alcohols
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DOI: 10.1021/acscatal.8b04567
Abstract: A highly selective formation of geometrically defined acyclic tri- and tetrasubstituted alkenes from inexpensive and readily available propargyl alcohols is described. Through vanadium oxo catalysis, tri- and tetrasubstituted α-chloro-, bromo-, and iodo-enone olefins can be… read more here.
Keywords: geometry; defined acyclic; tri tetrasubstituted; acyclic tri ... See more keywords