Dual Role of Anthranils as Amination and Transient Directing Group Sources: Synthesis of 2-Acyl Acridines.
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DOI: 10.1021/acs.orglett.8b01571
Abstract: The transient directing group promoted C(sp2)-H functionalization of benzaldehydes with anthranils by a cationic rhodium(III) catalyst is described. Notably, anthranils have been used as both transient directing groups and amination sources to afford 2-acyl acridines… read more here.
Keywords: acyl acridines; dual role; directing group; group ... See more keywords