Synthesis of chloroesters by the reaction of ethers with acyl chlorides catalyzed by ZnO
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DOI: 10.1007/s11696-020-01267-2
Abstract: An efficient method for the synthesis of chloroesters by the reaction of ethers with acyl chlorides catalyzed by nano-ZnO under solvent-free condition at room temperature was described. The method is compatible with a range of… read more here.
Keywords: acyl chlorides; reaction ethers; chlorides catalyzed; synthesis chloroesters ... See more keywords
Mechanochemical Synthesis of Ketones via Chemoselective Suzuki-Miyaura Cross-Coupling of Acyl Chlorides.
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DOI: 10.1021/acs.orglett.2c00519
Abstract: The direct synthesis of ketones via acyl Suzuki-Miyaura cross-coupling of widely available acyl chlorides is a central transformation in organic synthesis. Herein, we report the first mechanochemical solvent-free method for highly chemoselective synthesis of ketones… read more here.
Keywords: synthesis ketones; suzuki miyaura; synthesis; ketones via ... See more keywords
One-Step Synthesis of Acylborons from Acyl Chlorides through Copper-Catalyzed Borylation with Polystyrene-Supported PPh3 Ligand.
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DOI: 10.1021/acs.orglett.2c02305
Abstract: We developed a one-step synthesis of acylborons from both readily available acyl chlorides and bis(pinacolato)diboron through copper(I)-catalyzed borylation. Under the reaction conditions using tBuOLi, polystyrene-supported triphenylphosphine as a copper ligand was found to promote the… read more here.
Keywords: synthesis acylborons; one step; synthesis; borylation ... See more keywords
Phosphine–Borane Ligands Induce Chemoselective Activation and Catalytic Coupling of Acyl Chlorides at Palladium
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DOI: 10.1021/acscatal.0c04287
Abstract: Acyl chlorides are highly reactive and widely used substrates in catalytic cross-coupling reactions, but so far, site selectivity over other functional groups has remained an issue. In this work, P... read more here.
Keywords: induce chemoselective; phosphine borane; borane ligands; chemoselective activation ... See more keywords
Palladium-catalyzed sequential acylation/annulation of indoles with acyl chlorides using primary amine as the directing group
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DOI: 10.1039/d0nj04406g
Abstract: An efficient, palladium(ii)-catalyzed, C(sp2)–H acylation/annulation of indoles with acyl chlorides for the synthesis of substituted indolo[1,2-a]quinazolines is reported. read more here.
Keywords: annulation indoles; acyl chlorides; indoles acyl; palladium catalyzed ... See more keywords
Sequential hydrozirconation/Pd-catalyzed cross coupling of acyl chlorides towards conjugated (2E,4E)-dienones
Sign Up to like & getrecommendations! Published in 2023 at "Beilstein Journal of Organic Chemistry"
DOI: 10.3762/bjoc.19.17
Abstract: Dienones are challenging building blocks in natural product synthesis due to their high reactivity and complex synthesis. Based on previous work and own initial results, a new stereospecific sequential hydrozirconation/Pd-catalyzed acylation of enynes with acyl… read more here.
Keywords: chlorides towards; towards conjugated; sequential hydrozirconation; conjugated dienones ... See more keywords