Bis(acyl)phosphide - Ambidentate Ligands for the Synthesis of Group 14 and 15 Main Group Element Compounds.
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DOI: 10.1002/cplu.202200451
Abstract: The reactivity of the bis(acyl)phosphide ion [P(COR)2]- (BAP-, R = Ph, Mes) with silicon halides SiX4 (X = Cl, Br) and pnictogen chlorides ECl3 (E = As, Sb and Bi) was investigated. The reaction with… read more here.
Keywords: bis acyl; ambidentate ligands; phosphide ambidentate; acyl phosphide ... See more keywords
Homoleptic Uranium-Bis(acyl)phosphide Complexes.
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DOI: 10.1021/acs.inorgchem.2c00639
Abstract: The first uranium bis(acyl)phosphide (BAP) complexes were synthesized from the reaction between sodium bis(mesitoyl)phosphide (Na(mesBAP)) or sodium bis(2,4,6-triisopropylbenzoyl)phosphide (Na(trippBAP)) and UI3(1,4-dioxane)1.5. Thermally stable, homoleptic BAP complexes were characterized by single-crystal X-ray diffraction and electron paramagnetic… read more here.
Keywords: bis acyl; bis; acyl phosphide; spectroscopy ... See more keywords
Magnetism Studies of Bis(acyl)phosphide-Supported Eu3+ and Eu2+ Complexes.
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DOI: 10.1021/acs.inorgchem.2c02675
Abstract: A series of bis(acyl)phosphide-supported Eu complexes were synthesized (bis(acyl)phosphide = BAP). In this study, BAP ligands proved to be excellent ligands for the synthesis of both Eu3+ and Eu2+ molecular complexes. Sodium bis(mesitoyl)phosphide (Na(mesBAP)) and… read more here.
Keywords: eu3 eu2; bis acyl; bis; acyl phosphide ... See more keywords