Acyl Radicals in Environmental Chemistry: From Fundamental Mechanisms to Sustainable Water Treatment.
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DOI: 10.1021/acs.accounts.5c00554
Abstract: ConspectusWhile acyl radicals have been harnessed in synthetic chemistry since their discovery in 1932, their environmental applications remain largely unexplored. Conventional water treatment predominantly utilizes inorganic radicals (•OH, SO4•-, H•) for their potent redox capabilities.… read more here.
Keywords: acyl radicals; chemistry; water treatment;
1,2-Acylcyanation of Styrenes by Photoinduced Nickel Catalysis to Generate Acyl Radicals from Acyl Fluorides.
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DOI: 10.1021/acs.orglett.5c00761
Abstract: We report herein a photoinduced nickel-catalyzed 1,2-acylcyanation of styrenes with acyl fluorides and trimethylsilyl cyanide (TMSCN). Nickel(II) acyl complexes, formed from nickel(0) complexes and acyl fluorides, are photoexcited to generate acyl radicals via a ligand-to-metal… read more here.
Keywords: acylcyanation styrenes; acyl; generate acyl; acyl radicals ... See more keywords