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Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c02347
Abstract: The first bioinspired, enantioselective, and protecting group free total synthesis of the antibacterial sesquiterpenoid (-)-antroalbocin A (1) has been achieved in 12 steps (5.4% overall yield) from dimedone. An organocatalytic Robinson annulation gave rapid access…
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Keywords:
total synthesis;
antroalbocin;
acyl shift;
acyl ... See more keywords
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Published in 2019 at "Synthesis"
DOI: 10.1055/s-0037-1611367
Abstract: A stereoselective synthetic route to embellished cis-hydrindanes from simple aromatic precursors is described. Oxidative dearomatization, ring expansion, and photochemical 1,3-acyl shift are the key features of our approach. Oxidative dearomatization of o-(hydroxymethyl)phenols followed by π4s…
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Keywords:
acyl shift;
oxidative dearomatization;
embellished cis;
cis hydrindanes ... See more keywords