Articles with "acylation" as a keyword



Solubility and subcellular localization of the three Drosophila RDGC phosphatase variants are determined by acylation

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Published in 2018 at "FEBS Letters"

DOI: 10.1002/1873-3468.13163

Abstract: Protein phosphorylation is an abundant molecular switch that regulates a multitude of cellular processes. In contrast to other subfamilies of phosphoprotein phosphatases, the PPEF subfamily is only poorly investigated. Drosophila retinal degeneration C (RDGC) constitutes… read more here.

Keywords: acylation; solubility subcellular; subcellular localization; variants determined ... See more keywords

Site‐Selective Acylation of Vinylcyclopropanes under Visible‐Light Photocatalysis

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Published in 2024 at "Asian Journal of Organic Chemistry"

DOI: 10.1002/ajoc.202400325

Abstract: We herein disclose a protocol for linear‐selective ring‐opening acylation of a range of electron‐poor VCPs with α‐ketoacids by Ir‐photocatalyst. While electron‐poor VCPs could be sensitized with various radical species generated under different reaction conditions including… read more here.

Keywords: acylation; acylation vinylcyclopropanes; vinylcyclopropanes visible; visible light ... See more keywords
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Mild and eco-friendly chemoselective acylation of amines in aqueous medium using a green, superparamagnetic, recoverable nanocatalyst†

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Published in 2017 at "Applied Organometallic Chemistry"

DOI: 10.1002/aoc.3744

Abstract: Copper-grafted guanidine acetic acid-modified magnetite nanoparticles (Fe3O4@GAA-Cu(II)) as a green, superparamagnetic and recoverable nanocatalyst is found to promote quantitative N-acylation of various amines in a very short time with an equimolar amount of thioacetic acid… read more here.

Keywords: green superparamagnetic; superparamagnetic recoverable; recoverable nanocatalyst; acylation ... See more keywords

Selective Acylation of Proteins at Gly and Lys in His Tags

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Published in 2022 at "ChemBioChem"

DOI: 10.1002/cbic.202200359

Abstract: The chemical modification of proteins is of great importance in chemical biology, biotechnology, and for the production of modified biopharmaceuticals, as it enables introduction of fluorophores, biotin, half‐life extending moieties, and more. We have developed… read more here.

Keywords: selective acylation; gly lys; acylation; lys tags ... See more keywords

Enhancing the Acylation Activity of Acetic Acid by Formation of an Intermediate Aromatic Ester.

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Published in 2017 at "ChemSusChem"

DOI: 10.1002/cssc.201700394

Abstract: Acylation is an effective C-C bond-forming reaction to condense acetic acid and lignin-derived aromatic compounds into acetophenones, valuable precursors to fuels and chemicals. However, acetic acid is intrinsically an ineffective acylating agent. Here, we report… read more here.

Keywords: acetic acid; acylation activity; intermediate aromatic; acylation ... See more keywords

CO2-promoted direct acylation of amines and phenols by the activation of inert thioacid salts.

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Published in 2022 at "ChemSusChem"

DOI: 10.1002/cssc.202200227

Abstract: Herein we report a carbon dioxide-promoted synthetic approach for the direct amidation between unactivated thioacid salts and amines under mild conditions for wide range of sustrates.  The method afforded amides in good to excellent yields… read more here.

Keywords: thioacid salts; transition metal; carbon dioxide; co2 promoted ... See more keywords

Enzymatic acylation of flavone isolated from extractive of bamboo leaves with oleic acid and antioxidant activity of acylated product

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Published in 2019 at "Engineering in Life Sciences"

DOI: 10.1002/elsc.201800096

Abstract: This present study aims to establish a relatively cheap and effective method for preparation of ester of flavone isolated from bamboo‐leaf extracts. According to this method, the solubility of bamboo leaf extract in a lipid… read more here.

Keywords: antioxidant activity; flavone isolated; bamboo; acylation ... See more keywords

Enzyme-catalyzed acylation improves gel properties of rapeseed protein isolate.

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Published in 2020 at "Journal of the science of food and agriculture"

DOI: 10.1002/jsfa.10457

Abstract: BACKGROUND Although rapeseed protein isolate (RPI) possessed some good functional properties, the use of RPI as an ingredient in food industry is restricted mainly due to its inferior gelation. The purpose of this study was… read more here.

Keywords: rapeseed protein; rpi; microscopy; acylation ... See more keywords

Characterization of diverse lysine acylations in Bacillus thuringiensis: Substrate profiling and functional exploration

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Published in 2024 at "PROTEOMICS"

DOI: 10.1002/pmic.202300350

Abstract: Lysine acylation has been extensively investigated due to its regulatory role in a diverse range of biological functions across prokaryotic and eukaryotic species. In‐depth acylomic profiles have the potential to enhance comprehension of the biological… read more here.

Keywords: bacillus thuringiensis; acylation; diverse lysine; characterization diverse ... See more keywords

Sustainable Photocatalytic Acylation of Transition Metal Dichalcogenides with Atom Economy.

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Published in 2024 at "Small"

DOI: 10.1002/smll.202311045

Abstract: Transition metal dichalcogenides (TMDs) are promising 2D nanomaterials for diverse applications, but their intrinsic chemical inertness hinders their modification. Herein, a novel approach is presented for the photocatalytic acylation of 2H-MoS2 and 2H-MoSe2 , utilizing… read more here.

Keywords: acylation; transition metal; photocatalytic acylation; atom economy ... See more keywords

Acylation of methylfuran with Brønsted and Lewis acid zeolites

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Published in 2018 at "Applied Catalysis A: General"

DOI: 10.1016/j.apcata.2018.06.005

Abstract: Abstract The acylation of methylfuran has been investigated using Bronsted and Lewis acid zeolite catalysts. The highest reaction rate for acylation on a per gram basis is found on zeolite Beta with high aluminum content… read more here.

Keywords: acylation methylfuran; acid zeolites; lewis acid; acylation ... See more keywords