Rhodium(III)-Catalyzed Acylation of C(sp3)-H Bonds with Cyclopropenones.
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DOI: 10.1021/acs.orglett.7b01650
Abstract: Rh(III)-catalyzed activation and acylation of sp3 C-H bonds has been realized with diarylcyclopropenone as an acylating reagent. Both benzylic C-H in 8-methylquinolines and unactivated C-H in 2-alkylpyridines are applicable in this C-H acylation reaction, providing… read more here.
Keywords: acylation sp3; acylation; iii catalyzed; sp3 bonds ... See more keywords