Tuning acylthiourea ligands in Ru(II) catalysts for altering the reactivity and chemoselectivity of transfer hydrogenation reactions, and synthesis of 3-isopropoxy-1H-indole through a new synthetic approach
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DOI: 10.1016/j.jorganchem.2019.121087
Abstract: Abstract Ru(II)-p-cymene complexes (1–3) containing picolyl based pseudo-acylthiourea ligands (L1-L3) were synthesized and characterized. The crystallographic study confirmed the molecular structures of all the ligands (L1-L3) and complex 3. The catalytic activity of the complexes… read more here.
Keywords: chemoselectivity; ligands catalysts; reactivity; tuning acylthiourea ... See more keywords
Antitumor activity of Pd(II) complexes with N,S or O,S coordination modes of acylthiourea ligands
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DOI: 10.1016/j.poly.2020.114543
Abstract: Abstract Seven new complexes (1–7) of Pd(II) with N-alkyl- and N,N-dialkyl-N′-acylthioureas were prepared and characterized by elemental analysis and spectroscopic techniques. The crystal structures of the coordination compounds [PdCl(PPh3)(5-cloropiridyl-N′-benzoylthioureato-k2N,S)] (2), cis-[Pd(PPh3)2(N-morpholyn-N′-benzoylthioureato-k2O,S)]PF6 (4) and cis-[Pd(PPh3)2(N,N-diphenyl-N′-thiophenylthioureato-k2O,S)]PF6 (7)… read more here.
Keywords: pph3; coordination; tumor cells; antitumor activity ... See more keywords