C-H Borylation of Diphenylamines through Adamantane-1-carbonyl Auxiliary by BBr3.
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DOI: 10.1021/acs.orglett.0c02552
Abstract: A method for ortho-C-H borylation of diphenylamines using BBr3 as the boron source has been reported. The noncatalytic adamantane-1-carbonyl directed reaction exhibited site exclusivity and good functional group tolerance. Generally, the borylation occurred at the… read more here.
Keywords: adamantane carbonyl; diphenylamines adamantane; borylation diphenylamines; auxiliary bbr3 ... See more keywords
X-ray Structures and Computational Studies of Two Bioactive 2-(Adamantane-1-carbonyl)-N-substituted Hydrazine-1-carbothioamides
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DOI: 10.3390/molecules27238425
Abstract: Two biologically active adamantane-linked hydrazine-1-carbothioamide derivatives, namely 2-(adamantane-1-carbonyl)-N-(tert-butyl)hydrazine-1-carbothioamide) 1 and 2-(adamantane-1-carbonyl)-N-cyclohexylhydrazine-1-carbothioamide 2, have been synthesized. X-ray analysis was conducted to study the effect of the t-butyl and cyclohexyl moieties on the intermolecular interactions and conformation… read more here.
Keywords: adamantane carbonyl; adamantane; analysis; structures computational ... See more keywords