SYNTHESIS, STRUCTURE, AND ANTIVIRAL PROPERTIES OF NOVEL 2-ADAMANTYL-5-ARYL-2 H -TETRAZOLES
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DOI: 10.1007/6073
Abstract: The reaction of 5-aryl- NH -tetrazoles with adamantan-1-ol in concentrated sulfuric acid proceeds regioselectively with the formation of the corresponding 2-adamantyl-5-aryl-2 H -tetrazoles. Nitration of these compounds leads to 2-(adamantan-1-yl)-5-(3-nitroaryl)-2 H -tetrazoles. The structures and… read more here.
Keywords: novel adamantyl; adamantyl aryl; spectroscopy; synthesis structure ... See more keywords
Enantioseparation of P-Stereogenic 1-Adamantyl Arylthiophosphonates and Their Stereospecific Transformation to 1-Adamantyl Aryl-H-phosphinates
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DOI: 10.3390/molecules28041584
Abstract: A focused library of 1-adamantyl arylthiophosphonates was prepared in racemic form. An enantioseparation method was developed for P-stereogenic thiophosphonates using (S)-1-phenylethylamine as the resolving agent. Under optimized conditions, three out of the five arylthiophosphonates were… read more here.
Keywords: adamantyl arylthiophosphonates; stereogenic adamantyl; adamantyl aryl; enantioseparation stereogenic ... See more keywords