Symmetry-Adapted Synthesis of Dicopper Oxidases with Divergent Dioxygen Reactivity.
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DOI: 10.1021/acs.inorgchem.2c01898
Abstract: Artificial metalloenzymes have fed our understanding of how inorganic reactivities emerge, evolve, and diversify in protein environments. Herein, we created dinuclear copper oxidases by genetically encoding a metal-ligating unnatural amino acid (bpy-Ala) per protomer in… read more here.
Keywords: dioxygen; synthesis dicopper; dicopper; symmetry ... See more keywords