Markovnikov at Gold: Nucleophilic Addition to Alkenes at Au(III)
Sign Up to like & getrecommendations! Published in 2018 at "Organometallics"
DOI: 10.1021/acs.organomet.8b00218
Abstract: The reactivity of Au(OAcF)2(tpy) (1, OAcF = OCOCF3; tpy = 2-(p-tolyl)pyridine) toward a wide variety of different alkenes with various substitution patterns and different oxygen-based nucleophiles has been investigated. These reactions are two-step processes where… read more here.
Keywords: iii; addition; gold nucleophilic; addition alkenes ... See more keywords
Diethylzinc-Mediated Radical 1,2-Addition of Alkenes and Alkynes.
Sign Up to like & getrecommendations! Published in 2021 at "Organic letters"
DOI: 10.1021/acs.orglett.1c00669
Abstract: A novel diethylzinc-mediated radical 1,2-addition of perfluoroalkyl iodides to unactivated alkenes and alkynes is presented, which demonstrates a novel way to generate an ethyl difluoroacetate radical. This method is highly efficient and gives full conversions… read more here.
Keywords: addition alkenes; diethylzinc mediated; mediated radical; radical addition ... See more keywords