Formal oxidative addition of a C-H bond by a 16e iridium(i) complex involves metal-ligand cooperation.
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DOI: 10.1039/c8cc01885e
Abstract: The first example of oxidative addition of a C-H bond to a square planar d8-Iridium complex, without any external additive, such as an acid, is described. Our mechanistic investigations show that metal-ligand cooperation through aromatization-dearomatization… read more here.
Keywords: iridium complex; addition bond; ligand cooperation; metal ligand ... See more keywords