Palladium-Catalyzed Asymmetric 1,4-Addition of Diarylphosphines to α,β-Unsaturated Sulfonyl Fluorides
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DOI: 10.1055/a-2067-7071
Abstract: A Pd-catalyzed asymmetric phosphination of α, β-unsaturated sulfonyl fluorides was developed, and a series of tertiary phosphorus compounds were obtained in excellent yields and enantioselectivities (up to 99% ee). The chiral adduct can be further… read more here.
Keywords: unsaturated sulfonyl; palladium catalyzed; asymmetric addition; catalyzed asymmetric ... See more keywords
Palladium-Catalyzed Asymmetric 1,4-Addition of Diarylphosphines to α,β-Unsaturated Sulfonamides
Sign Up to like & getrecommendations! Published in 2018 at "Synthesis"
DOI: 10.1055/s-0036-1591593
Abstract: A pincer palladium-catalyzed asymmetric 1,4-addition of diarylphosphines to α,β-unsaturated sulfonamides was realized for the synthesis of chiral sulfonamide phosphines with up to 98% ee under mild conditions. read more here.
Keywords: catalyzed asymmetric; unsaturated sulfonamides; diarylphosphines unsaturated; palladium catalyzed ... See more keywords