Decarboxylative Radical Addition to Methylideneoxazolidinones for Stereocontrolled Synthesis of Selectively Protected Diamino Diacids.
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DOI: 10.1021/acs.orglett.1c02684
Abstract: Syntheses of stereochemically pure and selectively protected diamino diacids can be achieved by redox decarboxylation of distal N-hydroxyphthalimide esters of protected aspartic, glutamic or α-aminoadipic acids via radical addition to methylideneoxazolidinones. The products are useful… read more here.
Keywords: addition; diamino diacids; addition methylideneoxazolidinones; protected diamino ... See more keywords