CO Coupling Chemistry of a Terminal Mo Carbide: Sequential Addition of Proton, Hydride, and CO Releases Ethenone.
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DOI: 10.1021/jacs.9b07743
Abstract: The mechanism originally proposed by Fischer and Tropsch for carbon monoxide (CO) hydrogenative catenation involves C-C coupling from a carbide-derived surface methylidene. A single molecular system capable of capturing these complex chemical steps is hitherto… read more here.
Keywords: carbide; proton hydride; chemistry; sequential addition ... See more keywords