Does Reduction-Induced Isomerization of a Uranium(III) Aryl Complex Proceed via C-H Oxidative Addition and Reductive Elimination across the Uranium(II/IV) Redox Couple?
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DOI: 10.1021/acs.inorgchem.2c01563
Abstract: Reaction of the uranium(III) bis(amidinate) aryl complex {TerphC(NiPr)2}2U(Terph) (2, where Terph = 4,4″-di-tert-butyl-m-terphenyl-2'-yl) with a strong reductant enabled isolation of isomeric uranium(III) bis(amidinate) aryl product {TerphC(NiPr)2}2U(Terph*) (3, where Terph* = 4,4″-di-tert-butyl-m-terphenyl-4'-yl). In terms of connectivity,… read more here.
Keywords: oxidative addition; addition reductive; aryl complex; uranium ... See more keywords