Copper-catalyzed asymmetric 1,6-conjugate addition of in situ generated para-quinone methides with β-ketoesters.
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DOI: 10.1039/d2cc00146b
Abstract: A Cu-catalyzed asymmetric 1,6-conjugate addition of in situ generated para-quinone methides (p-QMs) with β-ketoester has been developed to construct a ketoester skeleton bearing an adjacent tertiary-quaternary carbon stereocenter in good yields and high enantioselectivities. This… read more here.
Keywords: situ generated; asymmetric conjugate; addition situ; conjugate addition ... See more keywords