Palladium-Catalyzed Addition of Trifluoroacetylsilanes to Alkenes and Allenes via the Cleavage of C-Si Bonds.
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DOI: 10.1021/acs.orglett.4c00595
Abstract: The palladium-catalyzed addition of trifluoroacetylsilanes to alkenes and allenes via the cleavage of the C-Si bonds is reported. When alkenes are used, cyclopropanation occurs to afford cyclopropane derivatives bearing CF3 and siloxy groups with a… read more here.
Keywords: alkenes allenes; palladium catalyzed; trifluoroacetylsilanes alkenes; addition trifluoroacetylsilanes ... See more keywords