Reactant Additive-Triggered Deactivation of Pd/γ-Alumina-Catalyzed Hydrogenation Reactions. A Reactivity and Adsorption Study
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DOI: 10.1021/acs.iecr.0c03238
Abstract: Deactivation of a Pd/alumina catalyst has been observed during the hydrogenation of α-methylstyrene and styrene. In both feedstocks, deactivation is caused by an additive, 4-tert-butylcatechol (TBC... read more here.
Keywords: deactivation alumina; deactivation; hydrogenation; reactant additive ... See more keywords
Additive-Triggered Chain Transfer to a Solvent in Coordination Polymerization
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DOI: 10.1021/acs.macromol.9b02495
Abstract: Low-molecular-weight polystyrene (LMPS) is the precursor of a brominated styrene oligomer that is used for small, precise, thin electrical components and an environmentally benign flame-retardant m... read more here.
Keywords: triggered chain; solvent coordination; coordination polymerization; transfer solvent ... See more keywords