Entry to 1,2,3,4-Tetrasubstituted Arenes through Addressing the "Meta Constraint" in the Palladium/Norbornene Catalysis.
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DOI: 10.1021/jacs.9b12355
Abstract: Arenes with four different contiguous substituents, i.e. 1,2,3,4-tetrasubstituted arenes, are commonly found in bioactive compounds, but they are non-trivial to access via conventional methods. Through addressing the "meta constraint" in the palladium/norbornene (Pd/NBE) cooperative catalysis,… read more here.
Keywords: addressing meta; tetrasubstituted arenes; palladium norbornene; meta constraint ... See more keywords