Stereo- and Regiospecific SN2′ Reaction of MBH Adducts with Isocyanoacetates: en Route to Transition-Metal-Free α-Allylation of Isocyanoacetates
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DOI: 10.1021/acsomega.2c07581
Abstract: Herein, we report that under mild and transition-metal-free conditions an unprecedented and practical SN2′ reaction of Morita–Baylis–Hillman adducts with isocyanoacetates takes place in a stereo- and regiospecific manner. This reaction which tolerates a wide variety… read more here.
Keywords: sn2 reaction; reaction; metal free; transition metal ... See more keywords