Valence Localization in Alkyne and Alkene Adducts of Synthetic [Fe4S4]+ Clusters.
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DOI: 10.1021/acs.inorgchem.2c01353
Abstract: Reported herein are alkyne and alkene adducts of synthetic [Fe4S4]+ clusters that model intermediates and inhibitor-bound states in enzymes involved in isoprenoid biosynthesis. Treatment of the N-heterocyclic carbene-ligated cluster [(IMes)3Fe4S4(OEt2)][BArF4] (IMes = 1,3-dimesitylimidazol-2-ylidene; [BArF4]- =… read more here.
Keywords: fe4s4 clusters; alkyne alkene; adducts synthetic; alkene adducts ... See more keywords