Adsorbate Organization Characterized by Sublevelset Persistent Homology.
Sign Up to like & getrecommendations! Published in 2023 at "Journal of chemical theory and computation"
DOI: 10.1021/acs.jctc.3c00090
Abstract: Interfacial adsorbate organization influences a variety physicochemical properties and reactivity. Surfaces that are rough, defect laden, or have large fluctuations (as in soft matter interfaces) can lead to complex adsorbate structures. This is amplified if… read more here.
Keywords: sublevelset persistent; adsorbate; liquid; persistent homology ... See more keywords
Functionalized N-Heterocyclic Carbene Monolayers on Gold for Surface-Initiated Polymerizations.
Sign Up to like & getrecommendations! Published in 2022 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.2c10985
Abstract: Although N-heterocyclic carbenes (NHCs) are superior to thiol adsorbates in that they form remarkably stable bonds with gold, the generation of NHC-based self-assembled monolayers (SAMs) typically requires a strong base and an inert atmosphere, which… read more here.
Keywords: functionalized heterocyclic; adsorbate; spectroscopy; surface initiated ... See more keywords
Technical Note: Classical and statistical thermodynamic treatment of adsorption and desorption kinetics and rates
Sign Up to like & getrecommendations! Published in 2021 at "Atmospheric Chemistry and Physics"
DOI: 10.5194/acp-2021-451
Abstract: Abstract. Adsorption and desorption represent the initial processes of the interaction of gas species with the condensed phase. It has important implications for evaluating heterogeneous (gas-to-solid) and multiphase chemical kinetics involved in catalysis, environmental interfaces,… read more here.
Keywords: gas; desorption; adsorption desorption; adsorbate ... See more keywords