Highly dynamic 1D coordination polymers for adsorption and separation applications
Sign Up to like & getrecommendations! Published in 2020 at "Coordination Chemistry Reviews"
DOI: 10.1016/j.ccr.2020.213661
Abstract: Abstract One-dimensional (1D) coordination polymers (CPs) are a class of materials with intriguing specific properties which however have been significantly overlooked, partially due to the monumental growth of research activities on their three-dimensional analogues, considered… read more here.
Keywords: adsorption separation; coordination polymers; dynamic coordination; highly dynamic ... See more keywords
A calcium-based microporous metal-organic framework for efficient adsorption separation of light hydrocarbons
Sign Up to like & getrecommendations! Published in 2019 at "Chemical Engineering Journal"
DOI: 10.1016/j.cej.2018.10.034
Abstract: Abstract Ideal metal-organic frameworks (MOFs) are those have not only significant adsorption separation performances but also excellent vapor and/or thermal stability. In this work, a calcium-based metal-organic framework with high vapor-stability and thermostability, Ca(squarate), was… read more here.
Keywords: separation; adsorption; metal organic; adsorption separation ... See more keywords
A rational design of cellulose-based heteroatom-doped porous carbons: Promising contenders for CO2 adsorption and separation
Sign Up to like & getrecommendations! Published in 2021 at "Chemical Engineering Journal"
DOI: 10.1016/j.cej.2021.130421
Abstract: Abstract The present work demonstrates a facile synthesis of cellulose-based novel microporous carbons (Cell-X) for environmental remediation by virtue of their application as CO2 adsorbents. The presence of heteroatoms (N, S) in highly porous carbon… read more here.
Keywords: co2 adsorption; cellulose based; adsorption separation; rational design ... See more keywords
Structural effects of microporous polymers on adsorption/separation of C1-C3 light hydrocarbons and CO2 in natural gas
Sign Up to like & getrecommendations! Published in 2022 at "Chemical Engineering Journal"
DOI: 10.1016/j.cej.2021.131985
Abstract: Abstract Microporous polymers (PAN-T1 and PAN-T2) with the similar polymer skeleton but considerably different BET surface areas from 1106 to 1563 m2 g-1, micropore surface areas from 250 to 868 m2 g-1 and total pore… read more here.
Keywords: co2; light hydrocarbons; c2h6; microporous polymers ... See more keywords
Strongly co-ordinated MOF-PSF matrix for selective adsorption, separation and photodegradation of dyes
Sign Up to like & getrecommendations! Published in 2022 at "Chemical Engineering Journal"
DOI: 10.1016/j.cej.2021.132561
Abstract: Abstract Though adsorption and separation processes using metal-organic frameworks (MOFs) for water treatment are highly promising, the disposal of adsorbed or rejected contaminants still remains a major challenge. Herein, we report photocatalytic (PC) MOF-embedded polysulfone… read more here.
Keywords: adsorption; selective adsorption; separation; mof psf ... See more keywords
Adsorption and separation of hexane isomers in metal-organic frameworks (MOFs): A computational study
Sign Up to like & getrecommendations! Published in 2021 at "Computational and Theoretical Chemistry"
DOI: 10.1016/j.comptc.2021.113164
Abstract: Abstract Density functional theory (DFT) calculations and molecular simulation methods were combined to investigate the adsorption behaviors of two kinds of MOF materials: ZIFs and UiO-66-R. The factors affecting the adsorption performance were analyzed and… read more here.
Keywords: hexane isomers; adsorption separation; separation hexane; adsorption ... See more keywords
Computational screening of heterocycle decorations in metal-organic frameworks for efficient C2/C1 adsorption and separation
Sign Up to like & getrecommendations! Published in 2020 at "Fuel"
DOI: 10.1016/j.fuel.2020.118431
Abstract: Abstract The separations of C2/C1 hydrocarbons are significant but challenging processes in petrochemical industry. Metal-organic frameworks (MOFs) have been considered as energy-efficient porous materials for gas separations owing to their moderate interactions with gas molecules.… read more here.
Keywords: heterocycle; adsorption; metal organic; separation ... See more keywords
Adsorption and separation of the C3 hydrocarbons on cationic FER zeolites: Effect of dual sites existence
Sign Up to like & getrecommendations! Published in 2019 at "Microporous and Mesoporous Materials"
DOI: 10.1016/j.micromeso.2019.01.032
Abstract: Abstract Adsorption and co-adsorption of propane and propene were investigated by combination of calorimetric-volumetric measurements with breakthrough experiments on alkali metal exchanged (Li, Na-, K-) FER zeolites with different Si/Al ratio. Effect of cation type… read more here.
Keywords: fer zeolites; separation hydrocarbons; adsorption; effect ... See more keywords
Novel porous carbon microtubes and microspheres produced from poly(CL-b-VbC) triarm block copolymer as high performance adsorbent for dye adsorption and separation
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Molecular Liquids"
DOI: 10.1016/j.molliq.2020.113565
Abstract: Abstract Dandelion-like and microtube-containing novel porous carbons were synthetized from brush type poly (e-caprolactone-b-4-vinyl benzyl chloride) (poly(CL-b-VbC)) triarm block copolymer with KOH (PCLVbK) and ZnCl2 (PCLVbZn) through optimized chemical activation at low temperature. These porous… read more here.
Keywords: adsorption; novel porous; porous carbons; adsorption separation ... See more keywords
Methane Adsorption and Separation in Slipped and Functionalized Covalent Organic Frameworks
Sign Up to like & getrecommendations! Published in 2018 at "Industrial & Engineering Chemistry Research"
DOI: 10.1021/acs.iecr.7b05031
Abstract: Understanding atomic-level mechanisms of methane adsorption in nanoporous materials is of great importance to increase their methane storage capacity targeting energy sources with low carbon emission. In this work, we considered layered covalent organic frameworks… read more here.
Keywords: adsorption; adsorption separation; methane adsorption; organic frameworks ... See more keywords
Creating Optimal Pockets in a Clathrochelate-Based Metal-Organic Framework for Gas Adsorption and Separation: Experimental and Computational Studies.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c00011
Abstract: The rational design and synthesis of robust metal-organic frameworks (MOFs) based on novel organic building blocks are fundamental aspects of reticular chemistry. Beyond simply fabricating new organic linkers, however, it is important to elucidate structure-property… read more here.
Keywords: adsorption; adsorption separation; clathrochelate based; metal organic ... See more keywords