Vibrational Perturbation of the [FeFe] Hydrogenase H-Cluster Revealed by 13C2H-ADT Labeling.
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DOI: 10.1021/jacs.1c02323
Abstract: [FeFe] hydrogenases are highly active catalysts for the interconversion of molecular hydrogen with protons and electrons. Here, we use a combination of isotopic labeling, 57Fe nuclear resonance vibrational spectroscopy (NRVS), and density functional theory (DFT)… read more here.
Keywords: adt labeling; vibrational perturbation; cluster; fefe hydrogenase ... See more keywords