Mn(III)‐salan/graphene oxide/magnetite nanocomposite as a highly selective catalyst for aerobic epoxidation of olefins
Sign Up to like & getrecommendations! Published in 2017 at "Applied Organometallic Chemistry"
DOI: 10.1002/aoc.3554
Abstract: A nanocomposite was synthesized using carbon-coated Fe3O4 nanoparticle-decorated reduced graphene oxide as a convenient and efficient supporting material for grafting of a manganese–reduced Schiff base (salan) complex via covalent attachment. The nanocomposite was characterized using… read more here.
Keywords: graphene oxide; catalyst aerobic; aerobic epoxidation; epoxidation ... See more keywords
Modification of Cu2+ into Zr-based metal–organic framework (MOF) with carboxylic units as an efficient heterogeneous catalyst for aerobic epoxidation of olefins
Sign Up to like & getrecommendations! Published in 2018 at "Molecular Catalysis"
DOI: 10.1016/j.mcat.2018.06.023
Abstract: Abstract A series of metal-organic framework (MOF) based catalysts for aerobic epoxidation were reported. A post-synthetic modification strategy using a solvothermal method enabled the incorporation of three different copper salts on a Zr-based MOF material… read more here.
Keywords: framework; metal organic; aerobic epoxidation; modification ... See more keywords
Biomimetic Aerobic Epoxidation of Alkenes Catalyzed by Cobalt Porphyrin under Ambient Conditions in the Presence of Sunflower Seeds Oil as a Co-Substrate
Sign Up to like & getrecommendations! Published in 2020 at "ACS Omega"
DOI: 10.1021/acsomega.9b03714
Abstract: In this work, a mild and sustainable catalytic aerobic epoxidation of alkenes catalyzed by cobalt porphyrin was performed in the presence of sunflower seeds oil. Under ambient conditions, the conversion rate of trans-stilbene reached 99%,… read more here.
Keywords: alkenes catalyzed; aerobic epoxidation; epoxidation; epoxidation alkenes ... See more keywords
Modulating Charges of Dual Sites in Multivariate Metal-Organic Frameworks for Boosting Selective Aerobic Epoxidation of Alkenes.
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.3c00460
Abstract: Selective aerobic epoxidation of alkenes without any additives is of great industrial importance but still challenging because the competitive side reactions including C═C bond cleavage and isomerization are difficult to avoid. Here, we show fabricating… read more here.
Keywords: selective aerobic; epoxidation alkenes; epoxidation; multivariate metal ... See more keywords