Excited State Engineering in Ag29 Nanocluster through Peripheral Modification with Silver(I) Complexes for Bright Near-Infrared Photoluminescence.
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.3c01259
Abstract: The optical property of an ionic metal nanocluster (NC) is affected by the ionic interaction with counter ions. Here, we report that the modification of trianionic [Ag29(BDT)12(TPP)4]3- NC (BDT: 1.3-benzenedithiol; TPP: triphenylphosphine) with silver(I) complexes… read more here.
Keywords: modification; ag29; silver; silver complexes ... See more keywords
Enantioseparation and chiral induction in Ag29 nanoclusters with intrinsic chirality†
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DOI: 10.1039/c9sc05299b
Abstract: The optical activity of a metal nanocluster (NC) is induced either by an asymmetric arrangement of constituents or by a dissymmetric field of a chiral ligand layer. Herein, we unveil the origin of chirality in… read more here.
Keywords: intrinsic chirality; chirality; enantioseparation chiral; ag29 ... See more keywords