Synthesis and characterization of partially substituted NHC supported alane adducts using triflate or chloride salts
Sign Up to like & getrecommendations! Published in 2021 at "Polyhedron"
DOI: 10.1016/j.poly.2020.115009
Abstract: Abstract Use of an aldiminium-based triflate salt as group transfer reagent to an N-heterocyclic carbene (NHC) adduct with alane [(IPr)AlH3] (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazole-2-ylidene) led to the substitution of a hydride by triflate and subsequently to… read more here.
Keywords: alane; ipr; chloride; characterization partially ... See more keywords
Reducing hybrid ligand-based alane and chasing aluminium(I): dialane and unusual transient dialumene.
Sign Up to like & getrecommendations! Published in 2024 at "Dalton transactions"
DOI: 10.1039/d4dt01798f
Abstract: In this work, an alane, [DNIAlH2] (1) (DNI = 3,3-dimethyl-2-[2-methyl-2-(2,6-diisopropyl-aniline)ethenyl]-3H-indolenine), stabilised by a hybrid ligand was reduced by Jones's Mg(I) ([(MesBDIMg)2]) and Roesky's Al(I) ([DippBDIAl:]). The resulting dialane compound [{DNI(H)Al}2] (2) was characterised using NMR… read more here.
Keywords: ligand based; alane; dialane; aluminium ... See more keywords