Synthesis, structure, and photoluminesence of the chloridoaluminates [BMIm][Sn(AlCl4)3], [BMPyr][Sn(AlCl4)3], and [BMIm][Pb(AlCl4)3].
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DOI: 10.1039/d0dt03766d
Abstract: [BMIm][Sn(AlCl4)3] (1) ([BMIm]: 1-butyl-3-methylimidazolium), [BMPyr][Sn(AlCl4)3] (2) ([BMPyr]: 1-butyl-1-methyl-pyrrolidinium), and [BMIm][Pb(AlCl4)3] (3) are obtained by reaction of SnCl2/PbCl2 in [BMIm]Cl/[BMPyr]Cl/AlCl3-based ionic liquids. The colourless crystals of the title compounds contain infinite 1∞[M(AlCl4)3]n- chains (M: Sn, Pb)… read more here.
Keywords: bmim alcl4; alcl4 bmpyr; bmpyr alcl4; alcl4 ... See more keywords
Peculiar diffusion behavior of AlCl4 intercalated in graphite from nanosecond-long molecular dynamics simulations
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DOI: 10.1088/1674-1056/ac0692
Abstract: The diffusion property of the intercalated species in the graphite materials is at the heart of the rate performance of graphite-based metal-ion secondary battery. Here we study the diffusion process of a AlCl4 molecule within… read more here.
Keywords: diffusion behavior; diffusion; alcl4; molecular dynamics ... See more keywords