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Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.1c04363
Abstract: Gold(I)-catalyzed stereoselective β-glycosylation of primary alcohols is achieved using the orthogonally protected mannosyl α-ortho-hexynylbenzoate (OABz) donors devoid of 4,6-O-tethering groups used in conventionally constructing β-mannosidic bonds. The potential of this methodology is showcased by the…
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Keywords:
acceptors trisaccharide;
mannosylation primary;
trisaccharide iteration;
alcohol acceptors ... See more keywords