Tandem Catalysis: Transforming Alcohols to Alkenes by Oxidative Dehydroxymethylation.
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DOI: 10.1021/jacs.8b06069
Abstract: We report a Rh-catalyst for accessing olefins from primary alcohols by a C-C bond cleavage that results in dehomologation. This functional group interconversion proceeds by an oxidation-dehydroformylation enabled by N, N-dimethylacrylamide as a sacrificial acceptor… read more here.
Keywords: oxidative dehydroxymethylation; dehydroxymethylation; alcohols alkenes; tandem catalysis ... See more keywords