Modelling phase behavior of triglycerides, diglycerides and monoglycerides related to biodiesel transesterification in mixtures of alcohols and CO2 using a polar version of PC-SAFT
Sign Up to like & getrecommendations! Published in 2020 at "Fluid Phase Equilibria"
DOI: 10.1016/j.fluid.2019.112303
Abstract: Abstract Soh et al. [1] showed that one can achieve high conversion (98%) of triglycerides to fatty acid methyl esters at 95 °C when carbon dioxide (CO2) is used as a co-solvent to enhance mixing of the… read more here.
Keywords: phase; saft; co2; phase behavior ... See more keywords
Synthesis Cu(I)–CN-based MOF with in-situ generated cyanogroup by cleavage of acetonitrile: Highly efficient for catalytic cyclization of propargylic alcohols with CO2
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DOI: 10.1016/j.mcat.2020.111190
Abstract: Abstract Developing a highly effective process for synthesis a cyano-bridged compound to avoid toxic organic or inorganic cyanides is very significant method for alleviating cyanides pollution. Here, a CN-based MOF catalyst (Cu(I)–CN–BPY) was synthesized by… read more here.
Keywords: synthesis; alcohols co2; propargylic alcohols; cyclization ... See more keywords
Palladium-Catalyzed Arylcarboxylation of Propargylic Alcohols with CO2 and Aryl Halides: Access to Functionalized α-Alkylidene Cyclic Carbonates.
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DOI: 10.1021/acs.orglett.7b00111
Abstract: A palladium-catalyzed, three-component reaction between propargylic alcohols, CO2, and aryl halides was developed whereby a sequential carboxylation, trans-oxopalladation of the C≡C bond by an ArPdX species, and a reductive elimination procedure afforded a series of… read more here.
Keywords: functionalized alkylidene; palladium catalyzed; propargylic alcohols; aryl halides ... See more keywords