Pivotal Neighboring-Group Participation in Substitution versus Elimination Reactions – Computational Evidence for Ion Pairs in the Thionation of Alcohols with Lawesson's Reagent
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DOI: 10.1002/ejoc.201700127
Abstract: The mechanism of the thionation of alcohols with Lawesson's reagent was explored through quantum chemical DFT methods. Evidence that carbocations are involved was found. The mechanism is completely different to that established recently for the… read more here.
Keywords: thionation; alcohols lawesson; lawesson reagent; thionation alcohols ... See more keywords